By Lawrence J. Berliner, Sandra S. Eaton, Gareth R. Eaton
The basis for knowing the functionality and dynamics of organic structures is wisdom in their constitution. Many experimental methodologies are used for selection of constitution, each one with exact utilities. The volumes during this sequence on Biological Magnetic Resonance emphasize the equipment that contain magnetic resonance. This quantity seeks to supply a serious evaluate of EPR tools for deciding on the distances among unpaired electrons. The editors invited the authors to make this a really sensible booklet, with particular numerical examples of the way experimental info are labored as much as produce a distance estimate, and real looking tests of uncertainties and of the variety of applicability, alongside with examples of the facility of the strategy to solution organic difficulties.
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Additional info for Biological Magnetic Resonance: Distance Measurements in Biological Systems by EPR
Eds. (1996). Protein Folds. A Distance-Based Approach. CRC Press, Boca Raton, Florida. Borbat, P. P. and Freed, J. H. (1999). Multi-quantum ESR and Distance Measurements. Chem. Phys. Lett. 313, 145-154. Brooks, C. L. , and Pettitt, B. , eds. (1988). Proteins: A Theoretical Perspective of Dynamics, Structure, and Thermodynamics. Advances in Chemical Physics, Vol. 71. Buck, M. and Karplus, M. (1999). Internal and Overall Peptide Group Motions in Proteins: Molecular Dynamics Simulations for Lysozyme Compared with Results from X-ray and NMR Spectroscopy.
Magnetic Exchange through Hydrogen Bonds: Structural and Magnetic Characterization 24 Sandra S. Eaton and Gareth R. Eaton of cis-Hydroxoaquachromium(III) Complexes of Tetradentate and Monodentate Ligands. Inorg. Chem. 33, 359-366. , and Kispert, L. D. (1994). ENDOR Data Tabulations, Ch. VI in Handbook of Electron Spin Resonance, Vol. 1, C. P. , and H. A. , AIP Press, American Institute of Physics, New York. , and Mehring, M. (1990). Pulsed ENDOR Spectroscopy in Solids, Ch. 4 in Modern Pulsed and Continuous-Wave Electron Spin Resonance.
Determination of Electron-Electron Interspin Distance by Electron Spin Echo and Saturation Recovery Electron Paramagnetic Resonance. Current Topics in Biophysics 20, 5-8. Eaton, S. , Law, M. , Eaton, G. , and Greenslade, D. J. (1979). MetalNitroxyl Interactions. 7. Quantitative Aspects of EPR Spectra Resulting from Dipolar Interactions. J. Magn. Reson. 33, 135-141. Eaton, S. , More, K. , Sawant, B. , and Eaton, G. R. (1983). Use of the Half-Field Transition to Determine the Interspin Distance and the Orientation of the Interspin Vector in Systems with two Unpaired Electrons.